HKU Engineering team invents novel Direct Thermal Charging Cell for Converting low-grade waste heat to usable electricity

Authored by hku.hk and submitted by Wagamaga

A demonstration of DTCCs by recovering waste heat from the heated pipe filled with hot water. Powered by ten DTCCs, the OLED HKU logo lighted up and the smart window changed color. The OLED is turned off while the smart window (right) became transparent again when power is disconnected.

Dr Tony Shien-Ping Feng says the Direct Thermal Charging Cell (DTCC) can power smart energy devices. Voltage generated from body heat is able to support major sensors such as health monitoring devices.

Dr Tony Shien-Ping Feng of the Department of Mechanical Engineering at the University of Hong Kong (HKU) and his team (from left to right: Wang Xun, Huang Yu-ting and Mu Kai-yu), invented the Direct Thermal Charging Cell (DTCC), which can convert low-grade heat to electricity.

Dr Tony Shien-Ping Feng of the Department of Mechanical Engineering at the University of Hong Kong (HKU) and his team invented a Direct Thermal Charging Cell (DTCC) which can effectively convert heat to electricity, creating a huge potential to reduce greenhouse effects by capturing exhaust heat and cutting down primary energy wastage.

The new invention is recently published in the prestigious journal Nature Communications (http://www.i-nanoeng.com/upload/2019/09/20190918160051.pdf), and the research has been featured in the Nature Communications Editors’ Highlights webpage. HKU’s Technology Transfer Office has filed for the invention’s US provisional patent and PCT (Patent Cooperation Treaty) patent.

Low grade heat is abundantly available in industrial processes (80 to 150°C), as well as in the environment, living things, solar-thermal (50 to 60°C) and geothermal energy. Over 60% of the world’s primary energy input, whether it is in the industrial process or domestic energy consumption, is wasted as heat. A majority of this loss as waste heat is regarded as low-grade heat.

The newly designed DTCC is a game-changing electrochemical technology which can open new horizons for applications to convert low-grade heat to electricity efficiently. It is a simple system with the basic unit sized only 1.5 sq.cm and thickness 1 to 1.5 mm. The cell is bendable, stackable and low cost.

DTCC can be used in HVAC (heating, ventilation, and air conditioning) system to recycle low-grade heat from the compressor and condenser into electricity for use in electrical devices. It can be integrated with the window frame to harvest solar thermal energy to power electrochromic windows, or used as portable devices to power iphones or life-saving equipment in the wilderness. With the increasing popularity of wearable technology, this system may one day harness body heat to power wearable electronic devices or medical devices for monitoring body health conditions like blood sugar levels and blood pressure.

Dr Feng said: “Efficient low-grade heat recovery can help to reduce greenhouse gas emission but current technologies to convert this heat to electricity is still far from optimum. DTCC yields a conversion efficiency of over 3.5%, surpassing all existing thermo-electrochemical and thermo-electric systems, which is either too costly or complicated, or too low in efficiency for everyday applications. DTCC is a revolutionary design with great potentials in smart and sustainable energy devices.”

The new thermal charging cell uses asymmetric electrodes: a graphene oxide/platinum (GO/Pt) cathode and a polyaniline (PANI) anode in Fe2+/Fe3+ redox electrolyte via isothermal heating operation without building thermal gradient or thermal cycle. When heated, the cell generates voltage via a thermo-pseudocapacitive effect of GO and then discharges continuously by oxidizing the PANI anode and reducing Fe3+ to Fe2+ under isothermal heating on cathode side till Fe3+ depletion. The energy conversion works continuously under isothermal heating during the entire charge and discharge process. The system can be self-regenerated when cooled down. This synergistic chemical regeneration mechanism allows the device cyclability.

The team is selected as one of the 16 finalists out of 300 applications and one of the only two finalists in Hong Kong competing in the Hello Tomorrow Regional Summit 2019, a competition for start-ups to adapt their research for real-world commercial uses, which will take place in Singapore this Thursday (November 7).

The invention has won the Championship in the HKU 2018 DreamCatchers 100K Entrepreneurship Competition. The team has established a start-up company, High Performance Solution, which is aided by the Technology Start-up Support Scheme for Universities (TSSSU). The company also joined the Incu-Tech 3-year programme at the Hong Kong Science Park and received its first revenue from the prototypes. The team has participated in the first X-plan roadshow of Talent Development Forum in Great Bay Area held by the Hong Kong X Foundation. It has also taken part at the Entrepreneurship Forum in Bahrain, Middle East.

DTCCs connected with waste water pipes can be converted to low-grade heat and used to power OLED and smart window. (video demonstration)

DTCC can harness body heat to power wearable electronic devices or medical devices for monitoring body health conditions. (video demonstration)

Presentation slides at the press briefing.

Direct thermal charging cell for converting low-grade heat to electricity

Xun Wang, Yu-Ting Huang, Chang Liu, Kaiyu Mu, Ka Ho Li, Sijia Wang, Yuan Yang, Lei Wang, Chia-Hung Su & Shien-Ping Feng

Dr Tony Feng Shien-ping, Department of Mechanical Engineering (Tel: 3917 2639; Email: [email protected])

Ms Celia Lee, Faculty of Engineering, HKU (Tel: 3917 8519; Email: [email protected])

Miss Bonnie Tsang, Faculty of Engineering, HKU (Tel: 3917 1924; Email: [email protected])

Orwellian1 on January 13rd, 2020 at 14:31 UTC »

If you want to skip all the normal BS in the article.

The new thermal charging cell uses asymmetric electrodes: a graphene oxide/platinum (GO/Pt) cathode and a polyaniline (PANI) anode in Fe2+/Fe3+ redox electrolyte via isothermal heating operation without building thermal gradient or thermal cycle. When heated, the cell generates voltage via a thermo-pseudocapacitive effect of GO and then discharges continuously by oxidizing the PANI anode and reducing Fe3+ to Fe2+ under isothermal heating on cathode side till Fe3+ depletion. The energy conversion works continuously under isothermal heating during the entire charge and discharge process. The system can be self-regenerated when cooled down. This synergistic chemical regeneration mechanism allows the device cyclability.

agate_ on January 13rd, 2020 at 12:43 UTC »

The efficiency of this process is less than 3%, and the Carnot limit means that no matter how you improve it it can’t use more than about 10% of the heat.

Rather than trying to turn industrial waste heat into electricity, it’s almost always going to be cheaper and more effective to reduce heat loss by using better insulation and heat exchangers.

22Maxx on January 13rd, 2020 at 12:43 UTC »

heat-to-electricity conversion efficiency of 2.8% at 70 °C (21.4% of Carnot efficiency) and 3.52% at 90 °C (19.7% of Carnot efficiency)

The cell can be self-regenerated when cooled down

Before anyone is getting too exited, this will not have a practical use in real world applications.