Dual-layer solar cell developed at UCLA sets record for efficiently generating power

Authored by samueli.ucla.edu and submitted by mvea
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Materials scientists from the UCLA Samueli School of Engineering have developed a highly efficient thin-film solar cell that generates more energy from sunlight than typical solar panels, thanks to its double-layer design.

The device is made by spraying a thin layer of perovskite — an inexpensive compound of lead and iodine that has been shown to be very efficient at capturing energy from sunlight — onto a commercially available solar cell. The solar cell that forms the bottom layer of the device is made of a compound of copper, indium, gallium and selenide, or CIGS.

The team’s new cell converts 22.4 percent of the incoming energy from the sun, a record in power conversion efficiency for a perovskite–CIGS tandem solar cell. The performance was confirmed in independent tests at the U.S. Department of Energy’s National Renewable Energy Laboratory. (The previous record, set in 2015 by a group at IBM’s Thomas J. Watson Research Center, was 10.9 percent.) The UCLA device’s efficiency rate is similar to that of the poly-silicon solar cells that currently dominate the photovoltaics market.

The research, which was published today in Science, was led by Yang Yang, UCLA’s Carol and Lawrence E. Tannas Jr. Professor of Materials Science.

“With our tandem solar cell design, we’re drawing energy from two distinct parts of the solar spectrum over the same device area,” Yang said. “This increases the amount of energy generated from sunlight compared to the CIGS layer alone.”

Yang added that the technique of spraying on a layer of perovskite could be easily and inexpensively incorporated into existing solar-cell manufacturing processes.

The cell’s CIGS base layer, which is about 2 microns (or two-thousandths of a millimeter) thick, absorbs sunlight and generates energy at a rate of 18.7 percent efficiency on its own, but adding the 1 micron-thick perovskite layer improves its efficiency — much like how adding a turbocharger to a car engine can improve its performance. The two layers are joined by a nanoscale interface that the UCLA researchers designed; the interface helps give the device higher voltage, which increases the amount of power it can export.

And the entire assembly sits on a glass substrate that’s about 2 millimeters thick.

“Our technology boosted the existing CIGS solar cell performance by nearly 20 percent from its original performance,” Yang said. “That means a 20 percent reduction in energy costs.”

He added that devices using the two-layer design could eventually approach 30 percent power conversion efficiency. That will be the research group’s next goal.

The study’s lead authors are Qifeng Han, a visiting research associate in Yang’s laboratory, and Yao-Tsung Hsieh and Lei Meng, who both recently earned their doctorates at UCLA. The study’s other authors are members of Yang’s research group and researchers from Solar Frontier Corp.’s Atsugi Research Center in Japan.

The research was supported by the National Science Foundation and the Air Force Office of Scientific Research. Yang and his research group have been working on tandem solar cells for several years and their accomplishments include developing transparent tandem solar cells that could be used in windows.

mr_chubaka on September 1st, 2018 at 22:30 UTC »

ELI5 why it's significant? (I thought that silicon solar cells can already achieve that)

haroldburgess on September 1st, 2018 at 21:19 UTC »

Is there a theoretical upper bound to the percentage of energy that can be converted?

mvea on September 1st, 2018 at 21:00 UTC »

The title of the post is a copy and paste from the title and third paragraph of the linked academic press release here :

Dual-layer solar cell developed at UCLA sets record for efficiently generating power

The team’s new cell converts 22.4 percent of the incoming energy from the sun, a record in power conversion efficiency for a perovskite–CIGS tandem solar cell.

Journal Reference:

Qifeng Han, Yao-Tsung Hsieh, Lei Meng, Jyh-Lih Wu, Pengyu Sun, En-Ping Yao, Sheng-Yung Chang, Sang-Hoon Bae, Takuya Kato, Veronica Bermudez, Yang Yang.

High-performance perovskite/Cu(In,Ga)Se2 monolithic tandem solar cells.

Science, 2018; 361 (6405): 904

DOI: 10.1126/science.aat5055

Link: http://science.sciencemag.org/content/361/6405/904

Perovskite/CIGS tandem cells

Tandem solar cells can boost efficiency by using more of the available solar spectrum. Han et al. fabricated a two-terminal tandem cell with an inorganicorganic hybrid perovskite top layer and a Cu(In,Ga)Se2 (CIGS) bottom layer. Control of the roughness of the CIGS surface and the use of a heavily doped organic hole transport layer were crucial to achieve a 22.4% power conversion efficiency. The unencapsulated tandem cells maintained almost 90% of their efficiency after 500 hours of operation under ambient conditions.

Abstract

The combination of hybrid perovskite and Cu(In,Ga)Se2 (CIGS) has the potential for realizing high-efficiency thin-film tandem solar cells because of the complementary tunable bandgaps and excellent photovoltaic properties of these materials. In tandem solar device architectures, the interconnecting layer plays a critical role in determining the overall cell performance, requiring both an effective electrical connection and high optical transparency. We used nanoscale interface engineering of the CIGS surface and a heavily doped poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) hole transport layer between the subcells that preserves open-circuit voltage and enhances both the fill factor and short-circuit current. A monolithic perovskite/CIGS tandem solar cell achieved a 22.43% efficiency, and unencapsulated devices under ambient conditions maintained 88% of their initial efficiency after 500 hours of aging under continuous 1-sun illumination.